Past and Current Models in Electrochemistry

Classical theories for electrochemical measurements and electrocatalysis.- Born model for ion solvation energies.- Models of the 1950s and 1960s.- Further explorations on the Gurney-Butler and Marcus-Hush themes.- Interplay of new spectroscopies and semiempirical molecular orbital theory: 1970s-1980s. The chemical bond is robust under perturbation.- Electronic structure picture of anode, cathode: Equilibrium with no current and conditions at steady state with current flowing.- Double layer formation on insulators.- Quantum theories for predicting reversible potentials and activation energies for electron transfer reactions, but still omitting surface charging and double layer polarization: 1980’s to present time.- Advanced First Principles Methods.- Advanced first principles studies involving hydrogen adsorption.- First principles modeling at the pzc including polarizable electrolyte: oxygen reactions on the Pt cathode and electroless copper deposition.- Recent studies of pH dependence of surface reactions.- Concluding comments and the view ahead.

• Erscheinungsdatum: 25.10.2025
• Autor/Autorin: Alfred Anderson
• Reihe: Chemistry and Material Science (R0)
• Format: E-Book
• Dateiformat: PDF
• Kopierschutz: Wasserzeichen
• Dateigröße: 12.8 MB
• Verlag: SPRINGER
• Sprache: Englisch
• Umfang: 216 Seiten
• ISBN: 9783031977916
• Lieferung: Sofort per Download
• Hinweis: Sofort per Download lieferbar. Kein physischer Versand.
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